Electrothermal Atomic Absorption Spectrometric Determination of Cadmium after Coprecipitation with Nickel Diethyldithiocarbamate.

Coprecipitation of trace metal ions in water with bismuth(III) diethyldithiocarbamate for an electrothermal atomic absorption spectrometric determination.

Determination of cadmium in river water by electrothermal atomic absorption spectrometry after internal standardization-assisted rapid coprecipitation with lanthanum phosphate.

Cadmium ranging from 1 - 8 ng could be coprecipitated quantitatively with lanthanum phosphate at pH 5 - 6 from up to 200 mL of river water samples spiked with 5 microg of indium as an internal standard. Cadmium and indium coprecipitated were measured by using electrothermal atomic absorption spectrometry. The cadmium content in the original sample solution could be determined by internal standa...

Atomic Absorption Spectrometric Determination of Lead after Extraction and Preconcentration with 5-Br-PADAP

Lead is quantitatively retained on 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP)-ammonium tetraphenylborate with microcrystalline naphthalene or by a column method in the pH range 4.0-6.0 from a large volume of aqueous solutions of various samples with preconcentration factor of 60. After filtration, the solid mass consisting of the lead complex and naphthalene was dissolved wi...

Determination of Aluminum in Dialysis Concentrates by Atomic Absorption Spectrometry after Coprecipitation with Lanthanum Phosphate

This method was developed for the determination of trace amounts of aluminum(III) in dialysis concentrates using atomic absorption spectrometry after coprecipitation with lanthanum phosfate. The analytical parameters that influenced the quantitave coprecipitation of analyte including amount of lanthanum, amount of phosfate, pH and duration time were optimized. The % recoveries of the analyte io...

Determination of cadmium in wine by electrothermal atomic absorption spectrometry.

A method is described for direct electrothermal atomic absorption spectrometric (ETAAS) determination of cadmium in untreated samples of wine. Pyrolytic graphite tubes and graphite tubes with standard L'vov pyrolytic platforms were tested as atomizers. The detection limit achieved was 0.08 microg L(-1) Cd in wine. The relative standard deviation for the concentration range from 0.2 to 10 microg...